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In situ coupling of Ti2O with rutile TiO2 as a core–shell structure and its photocatalysis performance
Journal article   Open access   Peer reviewed

In situ coupling of Ti2O with rutile TiO2 as a core–shell structure and its photocatalysis performance

Q. Wang, Jiajie Fan, Shilin Zhang, Yifan Yun, Jinhua Zhang, Peng Zhang, Junhua Hu, Lijie Wang and Guosheng Shao
RSC Advances, Vol.7(86), pp.54662-54667
11/2017

Abstract

The fabrication of high-performance, low-cost photocatalysis materials, which absorb in the visible-light region, is of significance for their practical applications. A Ti2O@TiO2 (rutile) core–shell structure was fabricated through dehydrogenation and oxidation from TiH2. Thermal analysis indicates that a bimodal oxidation behavior accounts for the formation of a bi-phasic composite. The response of the composite under UV and visible light was measured by PL (photoluminescence) spectra and a photo-degradation test. A pronounced improvement in photo-degradation performance is attributed to the synergistic function of exciton separation of the core–shell structure and the visible light response of the Ti2O cores.
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