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Modelling Thermal Degradation of Flame-Retarded Epoxy Resin Formulations under Different Heating Conditions
Conference proceeding   Peer reviewed

Modelling Thermal Degradation of Flame-Retarded Epoxy Resin Formulations under Different Heating Conditions

Everson Kandare, Baljinder K. Kandola, Richard A. Horrocks and John E. J. Staggs
FIRE AND POLYMERS V: MATERIALS AND CONCEPTS FOR FIRE RETARDANCY, Vol.1013, pp.368-386
ACS Symposium Series
01/01/2009

Abstract

Chemistry Chemistry, Multidisciplinary Science & Technology Physical Sciences Polymer Science
The thermal degradation kinetics of epoxy resin, triglycidyl-p-aminophenol (TGAP), and its flame-retarded formulations are investigated by thermogravimetric analysis (TGA) under oxidative conditions and are modelled using a simple global multi-step mechanistic scheme. Experimental TGA data acquired under non-isothermal conditions is used to optimise the kinetic parameters for selected boundary linear heating rates. These optimised kinetic parameters which adequately describe the thermal degradation process of epoxy resin formulations over the defined range of experimental conditions are then applied in the prediction of mass loss profiles of investigated materials under different heating conditions.

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